Reductive samarium (electro)catalysis enabled by SmIII-alkoxide protonolysis | Science

Reductive samarium (electro)catalysis enabled by SmIII-alkoxide protonolysis | Science

Samarium diiodide (SmI2) is a privileged, single-electron reductant deployed in diverse synthetic settings. However, generalizable methods for catalytic turnover remain elusive because of the well-known challenge associated with cleaving strong SmIII–O … Samarium diiodide (SmI2) is a privileged, single-electron reductant deployed in diverse synthetic settings. However, generalizable methods for catalytic turnover remain elusive because of the well-known challenge associated with cleaving strong SmIII–O …  Science

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